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| Faculty : |
School of Bio-Chemical Engineering and Technology (BCET) |
| Name : |
Dr. Pisanu Toochinda (Assistant Professor) |
| Position : |
Head of the School of Bio-Chemical Engineering and Technology and Coordinator of Chemical Engineering Curriculum |
| E - Mail : |
pisanu@siit.tu.ac.th |
| Phone Rangsit : |
+66 (0) 2986 9009, 2986 9101, 2564 3226 |
| Phone Bangkadi : |
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| Phone Extension : |
2309 |
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August 2003 Ph.D. Chemical Engineering, The University of Akron, Akron OH. Dissertation:Palladium and Copper: Environmentally Benign Catalysts for Oxidative Carbonylation and Photo Catalysis.
December 1999 M.S. Chemical Engineering, The University of Akron, Akron OH. Thesis: Carbamate Syntheses from the Oxidative Carbonylation reactions over Palladium on Carbon.
June 1995 B.S. Chemistry, Mahidol University, Bangkok, Thailand. Project: Interface behavior of natural latex and microencapsulation of fertilizer. |
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- 2008 Best Teaching Award, Sirindhorn International Institute of Technology.
- 2004 Best Teaching Award, Sirindhorn International Institute of Technology.
- Recipient of Travel Award for 19th Conference on Catalysis of Organic Reaction, 2002.
- Recipient of Kokes Travel Award for 2001.
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Hydrogen production from alcohol reforming, Photo-catalytic synthesis of hydrocarbons from CO2/H2O, Photochemical solar cells, Gas-solid reactor design, Heterogeneous catalysis, Nano-material / zeolite syntheses, Bio-molecular imprinted materials. |
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The Development of a Novel Catalyst for Hydrogen Production from Methanol Steam Reforming
The shortage of energy is becoming an important problem for mankind and the research of renewable energy has emerged rapidly to solve this problem. One interesting renewable energy is the energy from hydrogen fuel cells. Therefore, one of the most important issues to be considered for the hydrogen fuel cell is effective hydrogen production. Hydrogen could be produced from reforming reactions of hydrocarbons such as methane, methanol, ethanol, dimethyl ether, etc. This research focuses on methanol reforming to produce hydrogen for fuel cells from the steam reforming reaction. Unfortunately, the process still requires a huge amount of energy in order to produce a high yield of hydrogen. This is a major drawback of hydrogen production from the reforming reaction. The objective of this research is to study the performance of various catalysts from different preparation methods to identify the proper catalyst for methanol reforming. The optimization of the catalytic reactor design and reaction conditions are also investigated to enhance the reaction system for effective hydrogen production from methanol reforming.
Carbon Dioxide Capture by Immobilized Amine over Solid Sorbents
The high performance of amine solid sorbents could provide the alternative for CO2 capture from power plant flue gases. The concept is to capture carbon dioxide (CO2) from a simulated flue gas system by a tubular reactor using immobilized amine species on different solid sorbent support (activated carbon, zeolites, agriculture product waste) at ambient conditions. The concepts of the material preparation are high performance of CO2 capture, cost effectiveness, and easy handling for various applications. The preliminary design of a scaled up plant for the CO2 capture from solid sorbents is also considered in the study.
Photocatalysis
CO2 emission has become a worldwide problem due to its potential impact on global warming. Photocatalytic reactions, which involve the combined use of photo energy and catalysts to convert reactants to products, provide a promising alternative to reduce CO2 and convert it into useful hydrocarbon products (e.g., methane and methanol). |
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AFFILIATIONS
- Member of North American Catalysis Society.
- Member of Pittsburgh-Cleveland Catalysis Society.
- Member of Organic Reaction Catalysis Society.
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SKILLS
- Expertise in the use and maintenance of FTIR, FT-Raman, UV-visible, MS, GC,
HPLC, SEM, TEM, AA and NMR.
- Operation of computer-based data acquisition systems.
- Operation of computer graphic illustration and photo editing
programs.
EXPERIENCE
Jan. 1998-2003 Research Assistant, The
University of Akron.
- Well versed in the formulation, preparation, characterization, and testing a
wide range of catalysts, including Group VIII metal-oxide, metal nanoparticle,
sol-gel, carbon and mesoporous based catalysts.
- Designed a novel technique involving the use of FTIR, GC, and MS for in situ
studies during catalytic reaction of carbamate and dicarbamate from oxidative
carbonylation reactions.
- Worked extensively with in situ transmission IR, GC, and compartment
modeling for determination of catalyst activities and selectivities, reaction
kinetics, adsorbates, and reaction mechanisms.
- Worked extensively with SEM and TEM for the surface characterization of
catalysts.
- Designed and developed a novel gas-solid oxidative carbonylation in batch
and continuous reaction systems for carbamate and carbonate syntheses.
- Investigated reactivity and selectivity of Group VIII metal and
zeolite-based catalysts for oxidative carbonylation reactions and photocatalytic
reduction of CO2 and H2O.
- CO2 adsorption study on carbon-supported sorbents.
- Experienced in design, development, and optimization of industrial process
and reactor scale up to pilot scale.
- Collaborated in the composition of EPA-, DOE-, and NSF-funded proposals and
reports.
Jan.-May 2000 Teaching Assistant, The University of
Akron.
- Assisted instructor of class in undergraduate Chemical Engineering
Laboratory (Zeolite synthesis).
Jan.-May 2001 Teaching Assistant, The University of
Akron.
- Assisted instructor of class in undergraduate Chemical Engineering
Laboratory (Distillation column).
Jan.-May 2002 Teaching Assistant, The University of
Akron.
- Assisted instructor of classes in undergraduate Chemical Engineering
Laboratory (Distillation column) and Material Science.
Nov. 2003 - Present Lecturer, Sirindhorn International Institute
of Technology, Thammasat University.
- Instruct classes in undergraduate Chemistry for Engineers , General Sciene I
and II, Pre-Mathematics, and Material & Energy Balance.
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- Development of low-cost amine-enriched solid sorbent for CO2 capture, with Thuy Thi Nguyen, Environmental Technology 33, 23 (2012), 2645-2651.
- Molecular dynamics simulations of UC781-cyclodextrins inclusion complexes in
aqueous solution, with Kanokthip Boonyarattanakalin; Wolschann, Peter; and
Luckhana Lawtrakul, European Journal of Pharmaceutical Sciences 47, 4(2012),
752-758.
- Development of Ni/Al2O3 with urea catalysts for ethanol-steam reforming,
with P. Vacharapong; N. Umaree; R. Rojanasom; and D. Kamkoong, Proceedings of the Pure and
Applied Chemistry International Conference 2011 (PACCON2011) [CD-ROM], 5-7
January 2011, Bangkok, Thailand, pp. 192-195.
- The Role of Urea in Cu–Zn–Al Catalysts for Methanol Steam Reforming, with
Suparoek Henpraserttae and Pimpa Limthongkul, Monatshefte für Chemie, 141, 3
(2010) 269-277.
- Development of Low cost Solid Sorbent Using Agriculture Wastes for
CO2 Sequestration: A Study on the Effect of Mixing Amines and
Glycerol, with Thawatchai Jarunchart, Phongkrit Mangosol, M. Krikrabkreaw, and
Maruay Kittiyawat, Proceedings of Pure and Applied Chemistry International
Conference (PACCON 2010), 21-23 January 2010, Ubon Ratchathani, Thailand. pp.
247-250.
- Roles of Urea and Zirconia in Cu-Zn/Al2O3 for Methanol-steam Reforming, with
Chaichan Siriruang, Pumiwat Vacharapong, Sakdipong Ajavakom, and Thanawan
Sumonsart, Proceedings of Pure and Applied Chemistry International Conference
(PACCON 2010), 21-23 January 2010, Ubon Ratchathani, Thailand. pp. 251-254.
- Assessment of Mixed Basis Set and ONIOM Methods on the Activation Energy of
Ring Opening Reactions of Substituted Cyclobutenes with Y. Tantirungrotechai, S.
Roddecha and K. Punyain, Journal of Molecular Structure: THEOCHEM, 893,
1-3(2009) 98-105.
- Effects of Preparation of Cu/Zn Over Al2O3 Catalysts
for Hydrogen Production from Methanol Reforming, with Suparoek Henpraserttae,
Suranaree Journal of Science and Technology, 16, 2 (2009) 103-112.
- Development of Low Cost Amine-Enriched Solid Sorbent for CO2 Capture, with
Chaichan Siriuang, Proceedings of the Pure and Applied Chemistry International
Conference (PACCON 2009), 14-16 January 2009, Phitsanulok, Thailand. pp.
108-111.
- Development of Low Cost Solid Sorbent using Agriculture Wastes for
CO2 Sequestration with Thawatchai Jarunchart, Proceedings of the
2nd Thammasat University International Conference on Chemical,
Environmental and Energy Engineering (TU ChEEE 2009) [CD-ROM], 3-4 March 2009,
Bangkok, Thailand. pp. 108-113.
- Modeling of Methanol Steam Reformer to Produce Hydrogen for Fuel Cell
Application, with Rapeepong Suwanwarangkul; Sumittra Charojrochkul; Nawat
Kujareevanich; Opart Sanmontrikul; and Sakchai Kanchananiyom, Proceedings of the
1st Thammasat University International Conference on Chemical,
Environmental and Energy Engineering (TU ChEEE 2008) [CD-ROM], 4 March 2008,
Bangkok, Thailand. 6 p.
- Photocatalytic Synthesis of Hydrocarbon from CO2 and
H2O over Pt/TiO2. Proceedings of International Conference
on Engineering Applied Sciences, and Technology (ICEAST 2007) [CD-ROM] 21-23
November 2007, Bangkok, Thailand. Paper No. 54, pp. 838-841.
- Environmentally Benign Carbamate Synthesis,with Steven Chuang, Industrial
& Engineering Chemistry Research 43 (2004) 1192-1199.
- CO2 Capture by Amine-Enriched Fly Ash Carbon Sorbents with M.
Gray, K. Champagne,Y.Soong, R.Stevens,and S.Chuang,Separation and Purification
Technology 35,1(2004)31-36.
- Carbamate and Dicarbamate syntheses from CO/O2/Methanol/Amines,
with Steven S. C. Chuang and Yawu Chi, in Catalysis of Organic Reactions,
Morrell,D.G.ed.2003, pp.369-378.
- Synthesis of Carbamate through Low Pressure Heterogeneous Oxidative
Carbonylation of Amines, with Steven S. C. Chuang, Yawu Chi, and Bei Chen, WO
0288050,2002.
- Low-Pressure Oxidative Carbonylation of Aniline with Pd/C and Ag-Pd/C, with
Steven S.C.Chuang and Mahesh Konduru, Green Chemistry: Recent Advances in
Chemical Processing, ACS Publications, 2001.
- Novel amine enriched solid sorbents for carbon dioxide capture, with
Y.Soong, M.Gray, R.Siriwardane, K. Champagne, R. Stevens,and S. Chuang in
Environmental Challenges for Fossil Fuel Combustion and Greenhouse Gas Control
and Utilization; edited by M.Mercedes Maroto-Valer, Chunshan Song,and Yee Soong;
KluwerAcademic/Plenum Publishers, 2001.
- Environmentally Benign Carbonylation of Aniline and Nitrobenzene,with Steven
S.C.Chuang, Y.Chi, and M.Konduru, Stud.Surf.Catal., Proceedings of the
12th International Congress on Catalysis, Elsevier Publishers,
2000.
SELECTED PRESENTATIONS
- Environmentally Benign Isocyanate Synthesis,with Steven S.C.Chuang and
Mahesh Konduru, presented at 16th North American Meeting of the
Catalysis Society, Boston, May 30- June 04 1999.
- Carbamate synthesis from gas-solid oxidative carbonylation reaction over
Pd/C,with Steven S. C. Chuang,presented at 38th Spring Symposium of
the Pittsburgh-Cleveland Catalysis Society, Pittsburgh, PA, May 3-4 2000.
- Novel Chemical processes for Carbamate and Dicarbamate Synthesis from the
Gas-Liquid-Solid Oxidative Carbonylation, with Steven S. C. Chuang, presented at
17th North American Meeting of the Catalysis Society, Toronto, June
03-08 2001.
- Carbamate and Dicarbamate Syntheses from CO/O2/Methanol/Amines
19th Organic Reaction Catalysis Society,San Antonio, TX, April 2002.
- Photo-Catalytic Synthesis of Hydrocarbons from CO2/H2O
over Cu-Based Catalysts with Steven S. C. Chuang, presented at 18th North
American Meeting of the Catalysis Society, Cancun, Mexico, June 1-6
2003.
REFERENCES Provided upon request |
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